Taylor Swift
The Grammy-winner played peek-a-boo in a J. Mendel crop top and skirt with slit combo.
Hillary Scott, Stevie Nicks
The singers hung close during the pre-show.
Luke Bryan & Caroline Bryan
The co-host's wife made a colorful splash on the red carpet.
Keith Urban
On the other end of the style spectrum, a solo Keith donned head-to-toe black.
Olivia Munn
The actress flaunted lots of skin in a vibrant Rem Acra gown.
Jewel
The singer paired her classic black and white color combo with a cherry red lip.
Kacey Musgraves
Do you think Lupita Nyong'o inspired her? The Grammy winner opted for a similar sky blue gown.
Sheryl Crow
The star was the definition of elegance in a patterned black gown.
Hunter Hayes
Think there was a memo sent out? Like many of his fellow singers, the 22-year-old opted for a gray suit.
Jake Owen & Lacey Owen
The couple were a perfect match in their complementing ensembles.
Sarah Davidson
The Nashville Wives star looked radiant in a hot pink gown.
Jamie Lynn
The newlywed (in an eye-popping printed mini dress) hit her first red carpet since tying the knot last month.
Thomas Rhett
Class act! The singer topped his purple suit with a stylish polka dot bow tie.
Kelleigh Bannen
Now that's a shining star, alright! The singer glowed in a sequin number.

