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Natalie Stovall
The rising star played it safe in simple yet stunning black dress.
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Kellie Pickler
The singer wowed in a lavender Romona Keveza gown with crystal-adorned belt.
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The Band Perry
The trio—who will be opening tonight's show—were among the first to arrive on the red carpet in color coordinated grey and black duds.
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Danielle Bradbery
The Voice winner glowed in an embellished gown with sheer skirt.
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Brian Kelley & Tyler Hubbard
The duo went for a more casual vibe, opting for patterned tops and jeans. Tyler (right) wore Robert Graham Bowerbord Sport shirt under a basic black leather jacket.

