Kanye West and Kim Kardashian
While Kim expressed she had some nerves about the red carpet on Twitter (using the hashtag #butterflies), she and her hubby looked cool and confident, with the E! reality star rocking a metallic Balmain gown. As for Kanye, he wore blue jeans and contacts.
Zayn Malik and Gigi Hadid
The singer and model made their official red carpet debut as a couple at the May 2 event, with Zayn rocking robot arms, perfect for the night's Manus x Machina: Fashion in an Age of Technology theme.
Emily Blunt and Olivia Wilde
The expecting BFFs, who both rocked Michael Kors gowns, attended the event together, leaving husbands John Krasinski and Jason Sudeikis at home.
FKA Twigs and Robert Pattinson
After staying out of the spotlight for a bit, the engaged couple resurfaced at the glam event.
The Weeknd and Bella Hadid
The hot couple turned heads in all their all-black ensembles.
Karolina Kurkova & Georgina Chapman
The co-founder and designer of Marchesa couldn't help but give credit to the supermodel before meeting up on the red carpet. "Looks absolutely stunning," Georgina shared on Instagram.
Jenni Konner, Jenna Lyons and Lena Dunham
The Girls co-creators, and founders of the Lenny Letter, rocked matching black-tie looks (and glasses!) with J.Crew's creative director.
Nicole Kidman and Keith Urban
The country superstar and former American Idol host looked adoringly at his Oscar-winning wife, who was donning a cape, and we can't say we blame him.
Andy Cohen and Sarah Jessica Parker
The Bravo host gushed to E! News that he had "the hottest date" at the event, and then told us he was going to have his way with the Sex and the City star at the end of the night!
Zoe Saldana and Marco Perego
Talk about a train! The couple had all eyes on them on fashion's biggest night of the year.
Rosie Huntington-Whiteley and Jason Statham
The engaged couple rocked a classic look on the red carpet.
Carmelo and La La Anthony
The basketball star let his wife take the spotlight on the red carpet, with the TV personality telling E! News, "He doesn't require much!"
Alex Rodriguez and Anne Wojcicki
The baseball star and tech CEO sported a classic black and white look while making their relationship official.
Willow Smith and Jaden Smith
The brother-sister duo oozed coolness in all black at the NYC event.
CLICK: Check out all the celebs arriving at the 2016 Met Gala