Jay-Z and Beyoncé
It's hard to believe this couple, who are so perfectly coordinated in cool ensembles when out and about, have only walked the red carpet together a handful of times. Just imagine how amazing it would be if they ever hit the Cannes Film Festival arm-in-arm?
Angelina Jolie and Brad Pitt
No one can whip the shutterbugs into a frenzy on quite like Brangelina. When the duo are dressed to the nines on the red carpet, it's style perfection.
Prince William and Kate Middleton
This twosome are style royalty for a reason! The fashion icon looks better than ever with her prince at her side.
Justin Timberlake and Jessica Biel
This low-key couple make casual look chic and red carpet glamour look effortless.
Tom Brady and Gisele Bündchen
She's a supermodel, he could be a supermodel. So it's no surprise that the glamorous duo look like a real life Ken and Barbie dolls—especially when they coordinate.
Diane Kruger and Joshua Jackson
Not that Joshua was ever a bad dresser, but since hooking up with the ultra-chic actress, he's style has definitely seen a boost. Perhaps that's just what happens when you find your perfect match.
Victoria and David Beckham
If looking polished and posh were a contest, this duo would easily win.
Gwen Stefani and Gavin Rossdale
There's a good reason Gwen and Gavin have remained rock 'n' roll's reigning couple: They don't leave the house in anything that's not ultra-cool. They've even passed on their super-hip fashion sense to their kids!
Ellen DeGeneres and Portia de Rossi
Ah, Ellen and Portia: Each has a chic style that seems to complement the other's 99 percent of the time. So much so, they often look like twins!
Camila Alves and Matthew McConaughey
Both halves in this couple add just the right amount of funky, hippie flavor, which makes the overall effect effortlessly refreshing.
Olivia Palermo and Johanne Huebl
They may not be a household name, yet but this couple's style certainly is A-list. The definition of Upper East Side elegance, the pair always seem to be in perfectly chic sync.