Jennifer Aniston & Brad Pitt
The two famously split up in 2005 amid rumors that the actor was seeing his Mr. and Mrs. Smith costar Angelina Jolie.
Ashton Kutcher & Demi Moore
The couple was married for six years before the That '70s Show actor filed for divorce in 2012, a year and a half after they originally announced their split.
Scarlett Johansson & Ryan Reynolds
The two were officially single after a 2011 divorce. They wed at a Vancouver wilderness retreat in September 2008.
Katy Perry & Russell Brand
After just 14 months of marriage, the pop star and her British actor husband called it quits. Rumors ran rampant when both stars were spotted sans ring and spending the Christmas holidays separately. Russell filed the divorce papers, citing irreconcible differences.
Heidi Klum & Seal
The Hollywood power couple who celebrated almost seven years of marriage and three children together surprisingly announced that they have filed for separation.
Johnny Depp & Vanessa Paradis
The couple of 14 years confirmed their "amicable split" via the Pirates of the Caribbean star's publicist. Parents to 11-year-old Lily and 10-year-old Jack, Depp and Paradis asked that everyone "please respect their privacy and, more importantly, the privacy of their children."
Amy Poehler & Will Arnett
After nine years of marriage, the comedians shocked everyone when they announced the end of their relationship.
Jennifer Lopez & Marc Anthony
The Hollywood power couple shocked the world when they released a statement saying they decided to end their seven-year marriage. J.Lo and Marc have two children together, 3-year-old twins Emme and Max.
Katie Holmes & Tom Cruise
In July 2012, the brunette beauty filed for divorce from her actor hubby of five years—just days before his 50th birthday.